Catalytic reduction of nitrogen oxides in methane-fueled engine

Power plants – Internal combustion engine with treatment or handling of... – Methods

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60276, 60285, 60286, 60298, 60301, F01N 318, F01N 336

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active

055244327

ABSTRACT:
Nitrogen oxides are removed from the exhaust of an internal combustion engine which operates on a methane-containing fuel by reacting the nitrogen oxides and oxygen in the exhaust gas with a controlled amount of methane in the presence of a reducing catalyst. The catalyst preferably comprises a crystalline zeolite having a silicon to aluminum ratio of equal to or greater than about 2.5 which is prepared from a non-acid zeolite which is ion exchanged with a cation selected from the group consisting of cobalt, nickel, iron, chromium, and manganese. Methane for the reaction is provided as a portion of the methane-containing fuel. Carbon monoxide present in the exhaust gas is converted to carbon dioxide simultaneously with the reduction of nitrogen oxides.

REFERENCES:
patent: 5131224 (1992-07-01), Siewert et al.
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Castaldini, C. et al. "Environmental Assessment of Catalytic Reduction of Natural Gas-Fired Engines". Proc. Sympos. Combustion NOx Control 1985, vol. 2, pp. 57/1-57/16, 1987.
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Kosstrin, M. et al. "The Combustion of MSW-Derived Low-Btu Gas In An Internal Combustion Engine." Energy Biomass Wastes, 1988, vol. 11, pp. 217-236.
Wong, J. K. S. "Study of Mixtures of Methane and Carbon Dioxide as Fuels in a Single Cylinder Engine (CLR)." Mech. Eng. Report-Nat'l. Res. Council Canada, MP, MP-70, 27 pp., 1976.
Stolz, J. L. "Operating A Diesel Locomotive with Liquid Methane Fuel." ASME Energy Source Technology Conf. and Expo. 26-30 Jan. 1992. Houston, TX.

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