Catalytic production of aryl alkyl hydroperoxides by polynuclear

Details Catalytic production of aryl alkyl hydroperoxides by polynuclear Catalytic production of aryl alkyl hydroperoxides by polynuclear

1995-03-10

1996-04-02

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568569, 568573, 568574, C07C40908, C07C40910

Patent

active

055042562

ABSTRACT:
A method is provided for preparing organic hydroperoxides by oxidizing aryl alkyl hydrocarbons having a benzylic hydrogen with an oxygen containing gas using as a catalyst an oxo (hydroxo) bridged tetranuclear metal complex having a mixed metal core, one metal of the core being a divalent metal selected from Zn, Cu Fe, Co, Ni, Mn or mixtures thereof and another metal being a trivalent metal selected from In, Fe, Mn, Ga, and Al.

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Vincent, J., et al., Advances in Organic Chemistry, vol. 33, pp. 197-256 1989.
Lippard, S. J., Progress in Organic Chemistry, vol. 37, pp. 99-142 (1989).

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