Catalytic production of aryl alkyl hydroperoxides by manganese c

Details Catalytic production of aryl alkyl hydroperoxides by manganese c Catalytic production of aryl alkyl hydroperoxides by manganese c

1991-11-18

1993-02-02

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568573, 568575, 568577, C07C40922, C07C40900

Patent

active

051839458

ABSTRACT:
This invention relates to a process for preparing organic hydroperoxides by selectively oxidizing aryl alkyl hydrocarbons to their corresponding organic hydroperoxides using a catalyst certain tetranuclear manganese complexes. The process is carried out without appreciable decomposition by the catalyst of the resulting organic hydroperoxides, and without oxidation by the catalyst of other hydrocarbons present in the starting mixture.
The process of the present invention is useful for producing organic hydroperoxides, which themselves are useful as starting materials for a number of commercial reactions, for example, phenol and acetone production.

REFERENCES:
patent: 2954405 (1960-09-01), Hock et al.
patent: 4013725 (1977-05-01), Yonemitsa

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