Catalytic process for the selective oxidation of organic tertiar

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus containing

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568 17, 556 13, 556 16, 556 18, C07F 953

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active

059199849

ABSTRACT:
This invention concerns a process for the selective mono oxidation of organic tertiary polyphosphines to phosphine monooxides. These monooxides are useful as ligands for transition metals in the formation of transition metal catalysts.

REFERENCES:
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S. J. Berners-Price et al., Inorg. Chem., 26, 3383, 1987.
M. R. Mason et al., Organometallics, 11, 2212, 1992.
F. Ozawa et al., Chem. Lett., 2177, 1992.
CA:106:18696, abs of "Asimple synthesis and some synthetic applications of substituted phosphide and phosphinite anions" by Kabachnik, Synthesis (3) pp. 198-208, 1986.
CA::112:158360 abs of "Synthesis of vinyldiphenylsphosphine from diphenylphosphonic acid" by Bondarenko, Zh Obsch Khim 59(7), pp. 1533-1537, 1989.
CA:75:436318 abs of "Cyclopentadienyl (triphenylphosphine) ethylene rhodium and related compounds", by Graham, Inorg Chem 10(6) pp. 1165-1169, 1971.

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