Catalytic process for the selective formation of ethanol and met

Details Catalytic process for the selective formation of ethanol and met Catalytic process for the selective formation of ethanol and met

1981-09-15

1983-11-15

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

502327, 568698, 568902, 585733, C07C 6736, C07C 6914, C07C 2900, C07C 3108

Patent

active

044157495

ABSTRACT:
A process for the selective formation of ethanol and methyl acetate by contacting methanol, hydrogen and carbon monoxide with a catalyst comprising rhodium and iron in the reduced state deposited on a support of alumina containing a minor amount of an alkaline metal at reaction conditions correlated so as to favor the formation of a substantial proportion of ethanol and methyl acetate.

REFERENCES:
patent: 3248432 (1966-04-01), Riley et al.
patent: 3285948 (1966-11-01), Butter
patent: 3661949 (1972-05-01), Fenton
patent: 3717670 (1973-02-01), Schultz
patent: 4132734 (1979-01-01), Singleton
patent: 4133966 (1979-11-01), Pretzer et al.

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