Catalytic process for the preparation of polyacrylonitrile and a

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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260 326N, 260 47UA, 260 63N, 260 793M, 526 90, 526222, 526 72, 526225, 526328, 526342, 526347, C08F12044, C08F22044

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active

039592405

ABSTRACT:
A process for polymerizing acrylonitrile monomer or copolymerizing a mixture of acrylonitrile monomer and further ethylenically unsaturated monomers copolymerizable therewith, which comprises contacting the monomer or mixture of monomers in an aqueous medium at a temperature not exceeding 55.degree.C with a catalytic system comprising a watersoluble persulphate, a hydroxylamine mono- or disulfonate and a water-soluble salt of a variable valence metal, such as a ferrous salt.

REFERENCES:
patent: 2750357 (1956-06-01), Bredereck et al.
patent: 3065212 (1962-11-01), Milford et al.
patent: 3174954 (1965-03-01), Nakayama et al.
patent: 3635927 (1972-01-01), Johnston

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