Catalytic process for the preparation of isolongifolene

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By double-bond-shift isomerization

Reexamination Certificate

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C585S377000, C585S664000, C585S670000, C502S029000, C502S033000, C502S349000, C423S608000

Reexamination Certificate

active

07132582

ABSTRACT:
The present invention relates to a catalytic process for preparation of isolongifolene using nanocrystalline solid super acid. This process is an eco-friendly, single step, solvent free catalytic process for the preparation of a tricyclic sesqui-terpene hydrocarbon, isolongifolene. More particularly, the present invention provides a process for the catalytic isomerisation of longifolene to iso-longifolene using nano-crystalline sulfated zirconia as a solid super acid catalyst.

REFERENCES:
patent: 3718698 (1973-02-01), Hall
patent: 5304696 (1994-04-01), Khare et al.
patent: 5326923 (1994-07-01), Cooper et al.
patent: 6420305 (2002-07-01), Matsuzawa et al.
patent: 2327975 (1977-05-01), None
Database Caplus 'Online! Chemical Abstracts Service, Columbus, Ohio, US; Database Accession No. 2001:817301, XP002275587 & Xu Jingshi: “Study on Isomerisation of Longifolene Catalysed by Ti02/S208 2-” Huaxue Tongbao, No. 10, 2001, pp. 647-650, XP009027951, p. 648.

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