Catalytic process for removing sulfur dioxide from gas streams

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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423570, 252462, B01J 800, C01B 1700, C01B 1702

Patent

active

040228703

ABSTRACT:
This application describes a process for the catalytic reduction of sulfur dioxide in gas streams containing sulfur dioxide to elemental sulfur using a reducing gas such as hydrogen or, preferably, carbon monoxide, in a reactor charged with a material represented by the formula Ln.sub.2 O.sub.3 . Co.sub.2 O.sub.3, where Ln is either Y or Gd.
In a further aspect of this invention, a gas stream containing hydrogen sulfide or carbonyl sulfide and sulfur dioxide is passed through a reaction chamber charged with Ln.sub.2 O.sub.3 . Co.sub.2 O.sub.3, where Ln is either Y or Gd, to catalytically produce at a sufficiently elevated temperature elemental sulfur with concomitant reduction of the concentrations of the undesired hydrogen sulfide or carbonyl sulfide and sulfur dioxide.

REFERENCES:
patent: 3579302 (1971-05-01), Sefton
patent: 3717699 (1973-02-01), Nicklin et al.
patent: 3888792 (1975-06-01), Hughes
patent: 3931390 (1976-01-01), Palilla et al.

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