Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component
Patent
1975-07-16
1977-05-10
Thomas, Earl C.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Sulfur or sulfur containing component
423570, 252462, B01J 800, C01B 1700, C01B 1702
Patent
active
040228703
ABSTRACT:
This application describes a process for the catalytic reduction of sulfur dioxide in gas streams containing sulfur dioxide to elemental sulfur using a reducing gas such as hydrogen or, preferably, carbon monoxide, in a reactor charged with a material represented by the formula Ln.sub.2 O.sub.3 . Co.sub.2 O.sub.3, where Ln is either Y or Gd.
In a further aspect of this invention, a gas stream containing hydrogen sulfide or carbonyl sulfide and sulfur dioxide is passed through a reaction chamber charged with Ln.sub.2 O.sub.3 . Co.sub.2 O.sub.3, where Ln is either Y or Gd, to catalytically produce at a sufficiently elevated temperature elemental sulfur with concomitant reduction of the concentrations of the undesired hydrogen sulfide or carbonyl sulfide and sulfur dioxide.
REFERENCES:
patent: 3579302 (1971-05-01), Sefton
patent: 3717699 (1973-02-01), Nicklin et al.
patent: 3888792 (1975-06-01), Hughes
patent: 3931390 (1976-01-01), Palilla et al.
Gaudet Gary G.
Lingertat Helmut
Palilla Frank C.
GTE Laboratories Incorporated
Heller Gregory A.
Kriegsman Irving M.
Thomas Earl C.
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