Catalytic process for production of polyhydric alcohols in prese

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2605012, 26050116, C07C 2706, C07C 2916

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active

041905989

ABSTRACT:
Ammonium carboxylates having the general formula: ##STR1## wherein R is hydrogen or a substituted or unsubstituted hydrocarbon radical. The defined carboxylates promote the formation of alkane polyols in a homogeneous liquid phase mixture wherein hydrogen and carbon monoxide are reacted in the presence of a rhodium carbonyl complex at a temperature of from about 100.degree. C. to 375.degree. C. and a pressure of from about 500 psia to about 50,000 psia.

REFERENCES:
patent: 3957857 (1976-05-01), Pruett et al.

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