Catalytic process for polyhydric alcohols and derivatives

Details Catalytic process for polyhydric alcohols and derivatives Catalytic process for polyhydric alcohols and derivatives

1974-11-25

1977-03-22

Mars, Howard T.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252431R, 252431N, 252431L, 252431P, 252443, 260449L, 2604495, 260485G, 260488J, C07C 2706

Patent

active

040137007

ABSTRACT:
This invention relates to the manufacture of such valuable chemicals as polyhydric alcohols, their ether and ester derivatives, oligomers of such alcohols and monohydric alcohols and their ether and ester derivatives by reacting oxides of carbon and hydrogen in the presence of a quaternary phosphonium cation and a rhodium carbonyl complex.

REFERENCES:
patent: 3081357 (1963-03-01), Alderson et al.
patent: 3833634 (1974-09-01), Pruett et al.
Martinengo et al., Gazz, 102 (1972), 344-354.

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