Catalytic process for polyhydric alcohols and derivatives

Details Catalytic process for polyhydric alcohols and derivatives Catalytic process for polyhydric alcohols and derivatives

1979-02-05

1980-07-08

Mars, Howard T.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260449R, 2604495, 252431R, 252431N, 252431P, 252431L, C07C 2706, C07C 2916

Patent

active

042117194

ABSTRACT:
This invention relates to the manufacture of such valuable chemicals as polyhydric alcohols, their ether and ester derivatives, oligomers of such alcohols and monohydric alcohols and their ether and ester derivatives by reacting oxides of carbon and hydrogen in the presence of a quaternary ammonium cation and a rhodium carbonyl complex provided to the reaction as a rhodium carbonyl cluster anion which possesses an infrared spectrum which exhibits three intense wavelength bands between about plus and minus 10 cm.sup.-1 of about 1868 cm.sup.-1, about 1838 cm.sup.-1, and about 1785 cm.sup.-1 and said cation is present in the reaction mixture in about 0.8 to about 2.0 moles of cation for every six rhodium atoms present in the reaction mixture.

REFERENCES:
patent: 3576881 (1971-04-01), Senn
patent: 3725534 (1973-04-01), Reisch
patent: 3833634 (1974-09-01), Pruett et al.
patent: 3940432 (1976-02-01), Walker et al.
patent: 3957857 (1976-05-01), Pruett et al.
Martinengo et al., Gazz, 102, (1972), 344-354.

Affiliated with

Also associated with

Rating

Catalytic process for polyhydric alcohols and derivatives does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Catalytic process for polyhydric alcohols and derivatives, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Catalytic process for polyhydric alcohols and derivatives will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-560157