Catalytic process for making compounds having a non-Lewis acid/b

Chemistry of inorganic compounds – Boron or compound thereof – Nitrogen and hydrogen containing

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423279, 423283, 423285, 564 9, 564 10, 568 3, 568 4, C01B 3514

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048014397

ABSTRACT:
A process for preparing tractable preceramic precursors of Group IIIA metal/Group VA nonmetal compounds, such as BN, in which a first reactant containing a Group VA nonmetal to hydrogen bond, such as ammonia or an amine is reacted with a second reactant containing a Group IIIA metal to hydrogen bond, such as a metal hydride, in the presence of a metal catalyst that catalyzes dehydrocoupling of the bonds to form the precursor. Further reaction of the precursor in the presence of the catalyst forms oligomeric/polymeric forms of the precursor.

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