Catalytic preparation of tertiary butyl alcohol from tertiary bu

Details Catalytic preparation of tertiary butyl alcohol from tertiary bu Catalytic preparation of tertiary butyl alcohol from tertiary bu

1990-01-29

1991-06-18

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568715, 568840, 568864, C07C 29132, C07C 3112

Patent

active

050251139

ABSTRACT:
A tertiary butyl hydroperoxide feedstock, such as one prepared from the reaction product formed by the reaction of isobutane with molecular oxygen and which feedstock comprises tertiary butyl hydroperoxide dissolved in tertiary butyl alcohol, is charged to a catalytic decomposition zone where the tertiary butyl hydroperoxide is catalytically decomposed in the presence of a soluble catalyst system to provide a decomposition reaction product characterized by a high conversion rate and a high selectivity of tertiary butyl hydroperoxide to tertiary butyl alcohol, the catalyst system being composed of a soluble iron compound and a soluble ruthenium compound.

REFERENCES:
patent: 4551553 (1985-11-01), Taylor et al.
patent: 4922033 (1990-05-01), Sanderson et al.
patent: 4922034 (1990-05-01), Sanderson et al.

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