Catalytic preparation of nitroalkanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568947, C07C 7602

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active

044318421

ABSTRACT:
A process of making nitroalkanes which comprises reacting a lower alkanol, e.g. methanol, and nitric acid (HNO.sub.3) in the vapor phase in the presence of a catalyst which is an oxide or a salt of a metal of Group II of the periodic table, e.g. calcium chloride.

REFERENCES:
patent: 3115527 (1963-12-01), Drimus et al.
Hass et al., J. Am. Chem. Soc., vol. 76, pp. 2962 to 2964, (1954).
Coldiron et al., Ind. Eng. Chem., vol. 50, pp. 991 to 992, (1958).

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