Catalytic preparation of high molecular weight polysiloxanes

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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B01J 3108, B01J 3110

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045088454

ABSTRACT:
Polysiloxanes of relatively low molecular weight are catalytically polymerized/rearranged into high molecular weight polysiloxanes in the presence of a cationic catalyst comprising a porous, inorganic mineral particulate support having an average pore diameter in excess of 20 .ANG. and a pore volume ranging from 0.2 to 2 ml/g, said porous support being coated with less than 15 mg/m.sup.2 of a film of polymeric material comprising pendant sulfonic or phosphonic acid functions, and said polymeric material being characterized by an ion exchange capacity of less than 2 milliequivalents per gram.

REFERENCES:
patent: 4038213 (1977-07-01), McClure et al.
patent: 4222952 (1980-09-01), Vick
patent: 4250052 (1981-02-01), Smith
patent: 4414146 (1983-11-01), Olechowski et al.

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