Catalytic polymerization of CO/olefin with ortho polar substitut

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymer of an ethylenically unsaturated reactant with a...

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C08G 6702

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048431451

ABSTRACT:
An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises contacting under polymerization conditions the carbon monoxide and hydrocarbon in the presence of a catalyst composition formed from a compound of certain Group VIII metals, e.g., palladium, an anion of a non-hydrohalogenic acid having a pKa above about 2 but below about 6, and a bidentate ligand of phosphorus wherein at least one of the monovalent phosphorus substituents is aromatic and substituted in a position ortho to the phosphorus with a polar substitutent.

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