Catalytic polymerization of carbon monoxide with functional subs

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymer of an ethylenically unsaturated reactant with a...

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528220, 528222, 528223, 528224, 528225, 528235, 528242, 528243, 528271, C08G 6702

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048410209

ABSTRACT:
Novel copolymers and terpolymers are produced from carbon monoxide, a functionally-substituted ethylenically unsaturated compound wherein the functional substituent is separated from the ethylenic unsaturation by a divalent bridging group of at least one carbon, and optionally an ethylenically unsaturated hydrocarbon. The polymerization is conducted under polymerization conditions in the presence of a catalyst composition formed from a palladium compound, the anion of a non-hydrohalogenic acid having a pKa less than about 6 and a bidentate ligand of phosphorus or of nitrogen.

REFERENCES:
patent: 2495286 (1950-01-01), Brubaker
patent: 3689460 (1972-09-01), Nozaki
patent: 3780140 (1973-12-01), Hammer
patent: 4543440 (1985-09-01), Loomis
Kirk-Othmer, Encyclopedia of Chemical Technology, 2nd. Ed., vol. 12, 1967, pp. 132-133.

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