Catalytic poly alpha-olefin process

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585522, 585523, C07C 202

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active

046424105

ABSTRACT:
Alpha-olefins are oligomerized at high yields and rapid reaction rates by using a catalyst system comprising titanium halide, an organic halide and a trialkylaluminum compound. In performing the reaction, the titanium halide and the organic halide are first admixed, preferably in monomer. The reaction is initiated by admixing the aforesaid solution with the alpha-olefin containing the alkyl aluminum component. The reaction may be performed using a variety of organic halides at a varying alkyl aluminum to titanium compound ratio.

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