Catalytic oxychlorination of hydrocarbons to produce chlorocarbo

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Halogen or compound containing same

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502244, 502345, 502346, 502355, B01J 27122, B01J 2108, B01J 2370

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active

059728272

ABSTRACT:
Hydrocarbons, e.g., ethylene, are steady-state catalytically oxychlorinated into chlorocarbons, e.g., 1,2-dichloroethane, by fluidizing a fluidizable charge by directing a gaseous feedstream containing a hydrocarbon therethrough and therein oxychlorinating such hydrocarbon, the gaseous feedstream further comprising an oxygen-containing gas and gaseous hydrochloric acid and the fluidizable charge comprising immixture of a catalytically effective amount of an oxychlorination catalyst and particles of a catalytically and chemically inert solid substance, and which further comprises introducing a solution or suspension of a catalytically active copper compound into such fluidized charge during the oxychlorination reaction.

REFERENCES:
patent: 4339620 (1982-07-01), Cowfer et al.
patent: 5053567 (1991-10-01), Correia et al.

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