Catalytic oxidation of propylene to allyl acetate

Details Catalytic oxidation of propylene to allyl acetate Catalytic oxidation of propylene to allyl acetate

1986-02-27

1988-03-22

Garvin, Patrick P.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

502185, 502333, 502339, B01J 3104

Patent

active

047328835

ABSTRACT:
Propylene is oxidized directly to allyl acetate in the presence of acetic acid air or oxygen in the liquid phase under moderate reaction conditions employing a palladium-on-carbon catalyst which has been pre-treated be activating it with propylene at temperatures of greater than about 50.degree. C., preferably from 60.degree. to 150.degree. C., for a period of time sufficient to form a small but perceptible quantity of said activated catalyst, preferably for at least 10 minutes in the substantial absence of oxygen.

REFERENCES:
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patent: 3925452 (1975-12-01), Swodenk
patent: 3960930 (1976-06-01), Clarke
patent: 3970713 (1976-07-01), Scharfe
patent: 4016200 (1977-04-01), Onoda et al.
patent: 4093559 (1978-06-01), Fernholz et al.
patent: 4435598 (1984-03-01), Hinnenkamp
JACS, 98, 6913 (1976).
Discuss. Faraday Soc., 46, 98 (1968).
Hartley et al, The Chemistry of Platinum and Palladium, Wiley & Sons, pp. 386-390 & 412-417.

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