Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1977-02-07
1978-05-30
Garner, Vivian
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260526N, 260539R, C07C 5132, C07C 5704, C07C 5706, C07C 5708
Patent
active
040923550
ABSTRACT:
A method for the production of .alpha.,.beta.-unsaturated aliphatic carboxylic acids by the liquid phase oxidation of the corresponding .alpha.,.beta.-unsaturated aliphatic aldehydes, particularly acrolein and methacrolein, and the in situ decomposition of unsaturated intermediate peroxy (peroxide) compounds formed during oxidation, which comprises passing oxygen or an oxygen-containing gas through an inert solvent solution of the aldehyde at a suitable temperature and pressure in the presence of a catalytic amount of an inorganic or organic antimony salt. The solvent employed may also be mixed with water forming a heterogeneous solvent system.
REFERENCES:
patent: 2212900 (1940-08-01), Groll et al.
Kao Jar-lin
Leonard John Joseph
Atlantic Richfield Company
Garner Vivian
McCaslin Delbert E.
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