Catalytic isomerization of an internal double bond aliphatic mon

Details Catalytic isomerization of an internal double bond aliphatic mon Catalytic isomerization of an internal double bond aliphatic mon

1980-09-12

1981-09-15

Howard, Jacqueline V.

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

By double-bond-shift isomerization

252455R, 252471, C07C 525

Patent

active

042899192

ABSTRACT:
An aliphatic mono-olefin e.g. butene-2 is isomerized in the presence of a catalyst comprising essentially a small amount of a manganese oxide supported on an activated alumina to produce the corresponding terminal olefin selectively.

REFERENCES:
patent: 2304154 (1942-12-01), Doran
patent: 2818451 (1957-12-01), Myers
patent: 3501395 (1970-03-01), Miale
patent: 3509041 (1970-04-01), Miale
R. H. Ewell et al., J. of Am. Chem. Soc., vol. 63, No. 12, pp. 3460-3466, Dec. 17, 1941.
D. S. MacIver et al., J. Catalysis, 3, pp. 502-511, 1964.
Alumina Properties, Aluminum Co. of America, pp. 52-61.

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