Chemistry of inorganic compounds – Sulfur or compound thereof – Oxygen containing
Patent
1977-04-15
1979-10-16
Thomas, Earl C.
Chemistry of inorganic compounds
Sulfur or compound thereof
Oxygen containing
423230, 423573G, C01B 1750, B01D 5334
Patent
active
041713478
ABSTRACT:
A process for the conversion of H.sub.2 S to SO.sub.2 in a feed gas containing H.sub.2 S is effected by oxidation with air or oxygen at temperatures between 300.degree. and 900.degree. F. The oxidation is conducted in the presence of an extremely stable oxidation catalyst comprising an oxide and/or sulfide of vanadium supported on a non-alkaline porous refractory oxide. The preferred catalyst comprises between 5 and 15 wt.% V.sub.2 O.sub.5 on hydrogen mordenite or alumina. Hydrogen, carbon monoxide, light hydrocarbons, and ammonia present in the feed gas are not oxidized. The invention is especially contemplated for use in treating waste gases from geothermal steam power plants.
REFERENCES:
patent: 2083894 (1937-06-01), Connolly
patent: 2083895 (1937-06-01), Connolly
patent: 3997655 (1976-12-01), Reh et al.
patent: 4048293 (1977-09-01), Renault et al.
Hartman Richard C.
Sandford Dean
Thomas Earl C.
Union Oil Company of California
Wirzbicki Gregory F.
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