Catalytic incineration of hydrogen sulfide from gas streams

Chemistry of inorganic compounds – Sulfur or compound thereof – Oxygen containing

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423230, 423573G, G01B 1750

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active

040924041

ABSTRACT:
A process for the conversion of H.sub.2 S to SO.sub.2 is a feed gas containing H.sub.2 S is effected by oxidation with air or oxygen at temperatures between 300.degree. and 900.degree. F. The oxidation is conducted in the presence of an extremely stable oxidation catalyst comprising an oxide and/or sulfide of vanadium supported on a non-alkaline porous refractory oxide. The preferred catalyst comprises between 5 and 15 wt.% V.sub.2 O.sub.5 on hydrogen mordenite or alumina. Hydrogen, carbon monoxide and light hydrocarbons present in the feed gas are not oxidized. The invention is especially contemplated for use in treating waste gases from geothermal steam power plants.

REFERENCES:
patent: 1900751 (1933-03-01), Baehr
patent: 2083894 (1937-06-01), Connolly
patent: 2083895 (1937-06-01), Connolly
patent: 2756121 (1956-07-01), Grimes
patent: 2905523 (1959-09-01), Houdry et al.
patent: 3997655 (1976-12-01), Reh et al.

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