Catalytic hydrolysis of alkylene oxides

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07L 2700

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061370142

ABSTRACT:
A process for the preparation of alkylene glycols by reacting an alkylene oxide with water in the presence of a catalytic composition comprising a macrocyclic chelating compound complexed with an ionic compound the anion of which is catalytically effective under the reaction conditions. Preferably, the macrocycle is a crown ether or a cryptate and the anion is selected from the group of halogenides, carboxylates having from 1-20 carbon atoms, hydrogen carbonate, hydrogen sulphite, hydrogen phosphate and metalates.

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