Catalytic hydrogenation using amorphous metal alloy and a solven

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568396, 568388, 568404, 568903, C07C 4545

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active

060020474

ABSTRACT:
The present invention is concerned with a process for the catalytic hydrogenation of organic compounds on a catalyst of amorphous metal alloys and in a solvent, with the hydrogenation being carried out under near-critical or supercritical conditions of the solvent. The amorphous metal alloys can be produced by the shock cooling of alloy melts having eutectic solidification points. By hydrogenation at hydrogen partial pressures between 5 and 400 bar there is obtained outstanding space-time yields with high long-term stability of the catalytic activity.

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A. Baiker, "Glassy Metals in Catalysis", Topics in Appl. Physics, vol. 72, Ed. H. Beck and H.J. Guntherodt, Springer Verlag 1994.

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