Catalytic, hollow, refractory spheres

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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Details

502325, 502527, B01J 2340, B01J 3508

Patent

active

047014369

ABSTRACT:
Improved, heterogeneous, refractory catalysts are in the form of gas-impervious, hollow, thin-walled spheres (10) suitable formed of a shell (12) of refractory such as alumina having a cavity (14) containing a gas at a pressure greater than atmospheric pressure. The wall material may be itself catalytic or a catalytically active material coated onto the sphere as a layer (16), suitably platinum or iron, which may be further coated with a layer (18) of activator or promoter. The density of the spheres (30) can be uniformly controlled to a preselected value within .+-.10 percent of the density of the fluid reactant such that the spheres either remain suspended or slowly fall or rise through the liquid reactant.

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patent: 3798176 (1974-03-01), Ao
patent: 3978269 (1976-08-01), Martin
patent: 4039480 (1977-08-01), Watson et al.
patent: 4292206 (1981-09-01), Barnes, Jr. et al.
patent: 4344787 (1982-08-01), Beggs et al.

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