Catalytic formation of diarylcarbonates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbonate esters

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544357, 544401, C07C 6800

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052391051

ABSTRACT:
Diphenylcarbonate is produced by contacting phenol with phosgene or phenylchloroformate or mixture thereof in the presence of one or more heterogeneous catalysts. The catalysts include Group VB metal oxides: silicates of Groups IIA, IIIB, IVB, VB, and the lanthanide and actinide metals: tungsten oxides: and clays. The more preferred catalysts are silicates of yttrium, titanium, or zirconium.

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