Catalytic enantioselective addition of hydrocarbon equivalents t

Details Catalytic enantioselective addition of hydrocarbon equivalents t Catalytic enantioselective addition of hydrocarbon equivalents t

1988-05-11

1990-10-09

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 28, C07F 108

Patent

active

049622145

ABSTRACT:
The conjugate addition of Grignard reagents to alpha, beta-unsaturated carbonyl compounds using a series of novel catalysts is described. The catalysts comprise copper(I) complexes with ligand systems comprising either tropocoronand macrocycles or N,N'-dialkylsubstituted aminotroponeimines.

REFERENCES:
patent: 3052705 (1962-09-01), Brasen et al.
patent: 3177232 (1965-04-01), Muetterties
patent: 4471130 (1984-02-01), Katsuki et al.
Collman et al., Principles and Applications of Organotransition Metal Chemistry, Mill Valley, Calif., University Science Books, 1980.
Cotton et al., Advanced Inorganic Chemistry, New York; John Wiley & Sons, 1980.
Lipshutz et al., Tetrahedron, vol. 40, No. 24, pp. 5005-5038 (1984).
Fryduk, M. P. and B. Bosnich, J. Amer. Chem. Soc., 100:5491 (1978).
Villacorta, G. M. et al., J. Am. Chem. Soc., 107:6732-6734 (1985).
Dieter, R. K. and M. Tolkes, J. Am. Chem. Soc., 109:2040-2046 (1987).
Lipshutz, B. H. et al., J. Org. Chem., 49:3928-3938 (1984).
Corey, E. J. et al., J. Am. Chem. Soc., 108:7114-7116 (1986).
Davis, W. M. and S. J. Lippard, Inorg. Chem., 24:3688-3691 (1985).
Brunner. H. et al., J. Organometallic Chem., 295:211-221 (1985), and English Translation.
Posner, G. H. and M. Hulce, Tetrahedron Lett., 25(4):379-381 (1984).
Villacorta, G. M. and S. J. Lippard, Pure & Applied Chem., 58:1477-1484 (1986).
Villacorta, G. M. et al., Organometallics, 6:2426-2431 (1987).
Villacorta, G. M. and S. J. lippard, Inorg. Chem., 26:3672-3676 (1987).
Villacorta, G. M. and S. J. Lippard, Inorg. Chem., 27:144 (1988).
Villacorta, G. M. et al., J. Am. Chem. Soc., 110:3175-3182 (May 11, 1988).

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