Catalytic decarbonylation of esters

Details Catalytic decarbonylation of esters Catalytic decarbonylation of esters

1978-06-05

1980-09-30

Morgenstern, Norman

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C07C 4541

Patent

active

042255139

ABSTRACT:
Lower alkanoate esters of alcohols are contacted in the vapor phase and at elevated temperatures with certain metal oxide catalysts to produce the aldehyde or ketone corresponding to said alcohol. Preferred catalysts include nickel oxide, zinc oxide and chromium oxide.

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Matthews et al., "Jour. Org. Chem.", vol. 35, 1970, pp. 4158-4159.
Ipatieff et al., "Bull. Soc. Chim." (France), 1951, pp. 259-268.
Noto et al., "Trans. Faraday Soc.", vol. 63, Sep.-Dec., pp. 3081-3087, (1967).

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