Catalytic coupling of allylic compounds to substituted olefins

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2603435, 2604659, 260476R, 260533A, 260561N, 260614R, C07C 6952

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active

039667987

ABSTRACT:
Allylic compounds are carbon-to-carbon coupled to substituted olefins by contacting the two compounds in the presence of a catalyst system comprising a Group VIII metal component, a bromine or iodine component, and a Group VA component. The foregoing catalytic process also promotes the intra-molecular, carbon-carbon coupling of allylic and substituted olefin groups wherein both processes provide a method for producing sorbates and related compounds.

REFERENCES:
patent: 3113149 (1963-12-01), Probst et al.
patent: 3586714 (1971-06-01), Dubini et al.
patent: 3783136 (1974-01-01), Inukai et al.

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