Catalytic conversion of methane to higher hydrocarbons

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis

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585654, 585657, 585661, C07C 200

Patent

active

049182579

ABSTRACT:
A process for making ethylene, ethane and other higher hydrocarbons from methane is disclosed. In this process methane is contacted with oxygen in the presence of at least one metal of Group IB of the Periodic Table of the Elements, with the proviso that if the metal is copper an additional Group IB must be present, a metal-containing chloride or a metal-containing compound capable of being formed into a metal-containing chloride in situ, where the metal is manganese, an alkali metal, an alkaline earth metal or a rare earth metal of the lanthanide series, and a volatile halide.

REFERENCES:
patent: 4684800 (1987-01-01), Withers, Jr. et al.
Keller et al., Journal of Catalysis, 73, 9-19 (1982).
Chemical Abstract 107:39121t of Imamura et al., Chem. Express 2, No. 1, 49-52 (1987).

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