Catalytic conversion of allyl formate to carboxylic acids

Details Catalytic conversion of allyl formate to carboxylic acids Catalytic conversion of allyl formate to carboxylic acids

1986-05-23

1989-05-16

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

562590, 562606, C07C 5114, C07C 5112, C07C 53124, C07C 5512

Patent

active

048311910

ABSTRACT:
Allyl formate is substantially selectively converted to isobutyric acid, n-butyric acid and/or glutaric acid by bringing the alyl formate into contact with activated carbon in the presence of carbon monoxide, water and formic acid and a halide promoted group VIII soluble metal catalyst optionally in the presence of a solvent. Isobutyric and n-butyric acids are preferentially formed in the presence of relatively low concentrations of water and formic acid whereas glutaric acid is preferentially formed in the presence of relatively higher concentrations of water and formic acid.

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