Catalytic compositions for preparing amides and primary alcohols

Details Catalytic compositions for preparing amides and primary alcohols Catalytic compositions for preparing amides and primary alcohols

1986-02-13

1987-08-04

Evans, J. E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

502162, 556 23, 564128, 568852, C07C 2904, C07C 31125, C07C 3120

Patent

active

046847510

ABSTRACT:
A catalytic composition useful for producing amides and primary alcohols from nitriles and alkenes respectively, comprising in the first instance water, a suitable nucleophile, and MHCl[P(R).sub.3 ].sub.2 wherein M is platinum, palladium, or nickel, and R is CH.sub.3, CH.sub.3 CH.sub.2, or i-Pr and in the second instance comprising the same reagents but limited to R being CH.sub.3. The addition of a phase-transfer catalyst facilitates both reactions where the aqueous solubility of the nitriles or alkenes is limiting in the reaction.

REFERENCES:
patent: 2051144 (1936-08-01), Joshua et al.
patent: 2052095 (1936-08-01), Joshua et al.
patent: 3816550 (1974-06-01), Young et al.
patent: 3966798 (1976-06-01), Intille et al.
patent: 3988381 (1976-10-01), Dulog
patent: 3992456 (1976-11-01), Atkins et al.
patent: 4177210 (1979-12-01), Vanderkooi et al.
patent: 4322532 (1982-03-01), Braithwaite
patent: 4329500 (1982-05-01), Habermann
Article by Arnold and Bennett in Journal of Organometallic Chemistry, vol. 199 (1980), pp. 119-135.
Article by Villain, Gaset and Kalck in Journal of Molecular Catalysis, vol. 12 (1981), pp. 103-111.

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