Catalytic composition for biphase catalysis, in particular using

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585512, 585527, 585530, 585531, 502117, 502129, 502154, C07C 230

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057237123

ABSTRACT:
A novel catalytic composition comprises a mixture of lithium halide, a hydrocarbylaluminium halide and at least one compound of a catalytic element, in particular a nickel complex. The invention also concerns a process for the oligomerisation and co-oligomerisation of olefins catalysed by said composition. The catalytic mixture, which is liquid at the start of the reaction, is gradually transformed into a solid which is then readily separated from the reaction products.

REFERENCES:
patent: 3038892 (1962-06-01), Coover, Jr.
patent: 3125558 (1964-03-01), Hagemeyer, Jr. et al.
patent: 4187197 (1980-02-01), Kabanov et al.
patent: 4362650 (1982-12-01), Chauvin et al.
patent: 4996273 (1991-02-01), Van Der Huizen
patent: 5414160 (1995-05-01), Sato et al.

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