Catalytic composition for allylic oxidation of olefins

Details Catalytic composition for allylic oxidation of olefins Catalytic composition for allylic oxidation of olefins

1980-03-31

1982-01-05

Sneed, Helen M. S.

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

260429R, 2604381, 260446, 252431R, 562547, B01J 3112

Patent

active

043093108

ABSTRACT:
Olefins, such as propylene, are allylically oxidized to corresponding unsaturated aldehydes and carboxylic acids, such as acrolein and acrylic acid, by contacting the olefin with molecular oxygen at allylic oxidation conditions in the presence of a trifluoroalkyl sulfonate or phosphonate catalyst, such as a catalyst formed by the reaction of vanadyl oxide and trifluoromethyl sulfonate.

REFERENCES:
patent: 2329707 (1943-09-01), Farrington et al.
patent: 2346155 (1944-04-01), Denison et al.
patent: 2866732 (1958-12-01), Hoff et al.
patent: 2917528 (1959-12-01), Ramsey et al.
patent: 3219676 (1965-11-01), Wilkinson
patent: 3595890 (1971-07-01), Huerta et al.
patent: 3907706 (1975-09-01), Robins
patent: 3910976 (1975-10-01), Fein
patent: 3931242 (1976-01-01), Dawans et al.
Chemical Abstracts 76 25379n, (1972).
Chemical Abstracts 81 177827y, (1974).

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