Catalytic composition and a process for converting ethylene to l

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502117, 502126, 502132, 526142, 526153, 526161, B01J 3114, B01J 3138, C08F 460

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active

061036544

ABSTRACT:
A catalytic composition for the production of light alpha olefins by ethylene oligomerisation is produced by mixing a zirconium compound with an organic compound selected from the group formed by acetals and ketals, with an aluminium hydrocarbyl compound selected from the group formed by chlorine-containing or bromine-containing aluminium hydrocarbyl compounds and with an aluminium hydrocarbyl compound selected from tris-(hydrocarbyl)-aluminium compounds. Addition of a tris-(hydrocarbyl)-aluminium compound greatly increases the activity. A process for producing light alpha olefins by ethylene oligomerisation is also claimed.

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