Catalytic codimerization of norbornadiene with pentadiene

Details Catalytic codimerization of norbornadiene with pentadiene Catalytic codimerization of norbornadiene with pentadiene

1978-08-14

1980-02-26

O'Keefe, Veronica

Chemistry of hydrocarbon compounds

Alicyclic compound synthesis

Polycyclic product

585 14, 585 22, 149120, C07C 1332

Patent

active

041906101

ABSTRACT:
Catalytic codimerization of norbornadiene and 1,3-pentadiene yields an olefinic codimer which, after hydrogenation, has utility as a high energy missile fuel or a diluent for a higher viscous missile fuel. Used is a three-component homogeneous catalytic system, consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphina ethane and an alkyl aluminum chloride.

REFERENCES:
patent: 2875256 (1959-02-01), Hyman
Greco et al., J. Org. Chem., 35, No. 1, p. 271, 1970.
Carbonero et al., J. Org. Chem., 36, No. 10, p. 1443, 1971.

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