Catalytic codimerization of norbornadiene with pentadiene

Details Catalytic codimerization of norbornadiene with pentadiene Catalytic codimerization of norbornadiene with pentadiene

1978-08-14

1980-05-06

O'Keefe, Veronica

Chemistry of hydrocarbon compounds

Alicyclic compound synthesis

Polycyclic product

44 7R, 149120, C07C 1332

Patent

active

042017319

ABSTRACT:
Norbornadiene and 1,3-pentadiene are catalytically codimerized to an olefinic codimer using a three-component homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, triphenylphosphine and an alkyl aluminum chloride. The codimer, after hydrogenation, has utility as a high energy missile fuel or a diluent for a higher viscous missile fuel.

REFERENCES:
patent: 2875256 (1959-02-01), Hyman
Greco et al., J. Org. Chem., 35, No. 1, p. 271, 1970.
Carbonaro et al., J. Org. Chem. 36, No. 10, p. 1443, 1971.

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