Catalytic codimerization of norbornadiene with an acrylic acid e

Details Catalytic codimerization of norbornadiene with an acrylic acid e Catalytic codimerization of norbornadiene with an acrylic acid e

1977-07-01

1979-02-27

Myers, Jane S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

562498, C07C 6974

Patent

active

041420551

ABSTRACT:
Norbornadiene and an acrylic acid ester, e.g., methyl acrylate, are catalytically codimerized in the presence of a two-component homogeneous catalytic system consisting of nickel acetylacetonate and an alkyl aluminum chloride. The resulting codimer can be used as a precursor for a missile fuel. The ester portion of the acrylic acid ester is the radical RCH.sub.2 O-- wherein the R is an H or an alkyl containing up to 10 carbon atoms.

REFERENCES:
patent: 2940984 (1960-06-01), Applequist et al.
patent: 3271438 (1966-09-01), Cannell
patent: 3641175 (1972-02-01), Wilke et al.
Noyori et al., JACS 97:4 pp. 812-820 (1975).

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