Catalytic codimerization of norbornadiene with acrylonitrile

Details Catalytic codimerization of norbornadiene with acrylonitrile Catalytic codimerization of norbornadiene with acrylonitrile

1977-07-01

1978-08-15

Brust, Joseph Paul

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C12000, C07C12146

Patent

active

041071980

ABSTRACT:
Norbornadiene and acrylonitrile are catalytically codimerized in the presence of a three-component homogeneous catalytic system consisting of nickel acetylacetonate, triphenylphosphine and an alkyl aluminum chloride. The codimer can be used as a precursor for missile fuel.

REFERENCES:
patent: 2875256 (1959-02-01), Hyman et al.
patent: 2940984 (1960-06-01), Applequist et al.
patent: 3271438 (1966-09-01), Cannell
patent: 3340290 (1967-09-01), Blanchard
patent: 3641175 (1972-02-01), Wilke et al.
patent: 3956355 (1976-05-01), Ueshima
Noyori, et al., J.A.C.S., 97:4 (2-19-75) pp. 812-820.

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