Catalytic (CO)dimerization of alkyl acrylates

Details Catalytic (CO)dimerization of alkyl acrylates Catalytic (CO)dimerization of alkyl acrylates

1987-03-20

1988-11-22

Garvin, Patrick P.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

502155, 502162, 502154, 560202, B01J 3104, B01J 3102, B01J 3112

Patent

active

047866233

ABSTRACT:
The alkyl acrylates, e.g., methyl or ethyl acrylate, are improvedly dimerized, or codimerized with a conjugated diene, by contacting same with a catalytically effective amount of (a) at least one palladium source, (b) at least one organophosphorus(III) compound, and (c) at least one hydracid HY, the anion Y.sup.- of which does not coordinate with palladium ions.

REFERENCES:
patent: 4243829 (1981-01-01), Pittman et al.
patent: 4501822 (1985-02-01), Foley
patent: 4519954 (1985-05-01), Burrington et al.

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