Catalytic alkylation process

Details Catalytic alkylation process Catalytic alkylation process

1993-07-14

1994-07-26

Dees, Jose' G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 704

Patent

active

053328531

ABSTRACT:
This application concerns a process for alkylating, in a hydrocarbon solvent reaction medium, metalloidal substrates such as alkylating a chlorosilane with an alkyllithium containing 3 to 8 carbon atoms by conducting these reactions in the presence of a catalyst selected from primary and secondary alcohols, and their respective metal alkoxides, cyclic ethers, hydrocarbyl ethers, hydrocarbyl silyl ethers, and tertiary amines.

REFERENCES:
patent: 3420903 (1969-01-01), Smith
patent: 4593112 (1986-06-01), Takamizawa
patent: 4814474 (1989-03-01), Shirahata
W. Novis Smith, Journal of Organometallic Chemistry, 82 pp. 1-6.
A. Shirahata, Tetrahedron Letters, vol. 30, No. 46 pp. 6393-6394.

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