Catalytic alkylation of aromatic amines with alkanols

Details Catalytic alkylation of aromatic amines with alkanols Catalytic alkylation of aromatic amines with alkanols

1984-06-25

1986-07-08

Warren, Charles F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

C07C 8524

Patent

active

045994498

ABSTRACT:
Aromatic amines are alkylated by reaction with an alcohol in the presence of a Group VII-B metal oxide alkylation catalyst, preferably a major proportion of a Group VII-B metal oxide such as MnO.sub.2 in combination with a minor proportion of a Group VIII metal oxide such as Fe.sub.2 O.sub.3, so that alkylation of the aromatic amine occurs. Under most reaction conditions a considerable portion of the alcohol alkylating agent such as ethanol not consumed in the alkylation reaction passes through the reaction zone undecomposed and thus can be readily recovered for recycle or other use.

REFERENCES:
patent: 2515872 (1950-07-01), Heinemann
patent: 2580284 (1951-12-01), Deahl et al.
patent: 3819709 (1974-06-01), Murai et al.
patent: 3868420 (1975-02-01), Evans et al.
patent: 4183868 (1980-01-01), Radimerski et al.
patent: 4351958 (1982-09-01), Takahata et al.
Mailhe, et al., Comptes Rendus 166, 467-469 (1918).
Brown, et al., The Journal of the American Chemical Society 46, 1836-1839 (1924).
Shuikin, et al., J. Gen. Chem. (USSR), 4, 1444-1450 (1934) (Chemical Abstract Entry).
Nakagawa, et al., Japan Kokai 73-49,727 (Jul. 13, 1973) (Chemical Abstract Entry).
Takamiya, et al., Waseda University, Tokyo, Japan, 69, 21-25 (1975) (Chemical Abstract Entry).
Nakagawa, et al., Japan Kokai 77-48,969 (Dec. 15, 1977) (Chemical Abstract Entry).
Shuikin, et al., J. Gen. Chem. (U.S.S.R.), 6, 774-779 (1936) (Chemical Abstract Entry).
Inoue, et al., Sekiyu Gakkai Shi, 15, No. 5, 372-378 (1972) (Chemical Abstract Entry).
Ind. and Eng. Chem., 43, pp. 1579-1583 (1951).
Nippon Kagaku Kaishi, No. 11, pp. 1453-1457 (1979).

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