Catalysts for the polymerization of alpha-olefins

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 54, 502103, 502117, 526160, 526943, C07F 1700, C07F 700

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059170727

ABSTRACT:
A description follows of catalysts of the metallocene type which can be used in the (co)polymerization of alpha-olefins, particularly in the preparation of elastomeric copolymers of ethylene.

REFERENCES:
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patent: 5510502 (1996-04-01), Sugano et al.
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Chemical Abstracts, vol. 124, No. 4, Jan. 22, 1996, AN-30612x, T. Sunaga, et al., "Metallocene Compounds and Polymerization of Olefins Therewith", JP-A-07 173 208.
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Journal of Organometallic Chemistry, vol. 472, pp. 205-213, 1994, H.W. Bosch, et al., "Synthese Bicyclicsher Pentaalkylcyclopentadiene und Ihrer Metallkomplexe. Kristallstruktur Von Bis (1,2,3-Trimethylbicyclo (4.3.0) Nonadienyl)Eisen".
Journal of Organometallic Chemistry, vol. 378, pp. 153-161, 1989, P. Burger, et al., "Ansa-Metallocene Derivatives. XVIII. Chiral Titanocene Derivatives Accessible from Substituted Dihydropentalene and Azulene Precursors".
Journal of Organometallic Chemistry, vol. 465, pp. 175-179, 1994, R.L. Halterman, et al., "Electronic Effects of Bis(2-Aryl-4,5,6,7-Tetrahydroindenyl)Titanocene Dichlorides on the Catalytic Epoxidation of Trans-3-Hexene".

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