Catalysts for the oxidation of ethane to acetic acid processes o

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Phosphorus or compound containing same

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502206, 502211, 502215, 502308, 502311, 502321, 502349, 502353, 502312, B01J 27198, B01J 2719

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active

060135972

ABSTRACT:
An oxide catalyst comprising the elements Mo, V and Nb with small amounts of phosphorus, boron, hafnium, Te and/or As. The modified catalyst provides both higher selectivity and yield of acetic acid in the low temperature oxidation of ethane with molecular oxygen-containing gas. A process for the higher selective production of acetic acid by the catalytic oxidation of ethane with oxygen, in the presence of the improved catalyst.

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E.M. Thorsteinson et al. "The Oxidative Dehydrogenetion of Ethane ..." Journal of Catalysis vol. 52, pp. 116-132 (1978).

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