Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants
Patent
1979-04-05
1980-12-16
Shine, W. J.
Compositions
Preservative agents
Anti-oxidants or chemical change inhibitants
252416, 252420, 252462, 252464, 252468, 252469, 585417, 585500, 585656, 585943, B01J 2104, B01J 2310, B01J 2358, B01J 2364
Patent
active
042396581
ABSTRACT:
Novel regenerable catalyst-reagents, and a new and improved process utilizing said regenerable catalyst-reagents, for the conversion, and oligomerization of hydrocarbons, notably methane, at relatively low temperatures to produce products rich in ethylene or benzene, or both, usually in admixture with other hydrocarbons; and process for the regeneration of said catalyst-reagents. (a) The catalyst-reagents are multi-functional and are comprised of (1) a Group VIII noble metal having an atomic number of 45 or greater, nickel, or a Group I-B noble metal having an atomic number of 47 or greater; (2) a Group VI-B metal oxide which is capable of being reduced to a lower oxide, or admixture of metal oxides which includes one or more of such metal oxides; and, (3) a Group II-A metal selected from the group consisting of magnesium and strontium, composited with a suitably passivated, spinel-coated refractory support, notably an inorganic oxide support, preferably alumina; preferably calcium, composited with a suitably passivated, non-zinc containing spinel coated refractory support, notably an inorganic oxide support, preferably alumina.
REFERENCES:
patent: 2447016 (1948-08-01), Kearby
patent: 2992191 (1961-07-01), Erickson
patent: 3519573 (1970-07-01), Coe
patent: 4038209 (1977-07-01), Schoofs
patent: 4169815 (1979-10-01), Drehman
Mitchell, III Howard L.
Waghorne Robert H.
Exxon Research & Engineering Co.
Proctor Llewellyn A.
Shine W. J.
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