Chemistry of inorganic compounds – Nitrogen or compound thereof – Ammonia or ammonium hydroxide
Patent
1983-06-30
1986-11-18
Doll, John
Chemistry of inorganic compounds
Nitrogen or compound thereof
Ammonia or ammonium hydroxide
423645, C01C 104
Patent
active
046235329
ABSTRACT:
Bi-metallic alloys of iron and titanium are employed as catalysts for reacting nitrogen and hydrogen to yield ammonia. The binary alloy composition is first activated by removing surface oxides with hydrogen gas at elevated temperatures and pressures. The particle size of the catalyst may then be reduced by one or more dehydriding and hydriding steps.
REFERENCES:
patent: 1313314 (1919-08-01), Metzger
patent: 3382106 (1968-05-01), Jung et al.
patent: 3776855 (1973-12-01), Raymond et al.
Reilly et al, "Formation and Properties of Iron-Titanium Hydride", Inorganic Chemistry, vol. 13, No. 1 (1974), pp. 218-222.
Davis, Jr. Milton W.
Ozyagcilar Mehmet N.
Doll John
Langel Wayne A.
University of South Carolina
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