Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1998-05-06
2000-09-05
Geist, Gary
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568716, 502 64, 502 74, 502 77, 502 85, C07C 3760
Patent
active
RE0368563
ABSTRACT:
Zeolite catalysts useful for the production of phenol and its derivatives by oxidative hydroxylation of benzene and its derivatives by nitrous oxide, e.g. at temperatures of 225.degree.-450.degree. C., having substantially enhanced process characteristics resulting from hydrothermal treatment using a gas containing from about 3 to 100 mole percent water vapor, e.g. in nitrogen, at a temperature ranging from about 500.degree. to 1000.degree. C. Two hours of hydrothermal treatment has been shown to be effective.
REFERENCES:
patent: 4559314 (1985-12-01), Shihabi
patent: 4982013 (1991-01-01), Gubelmann et al.
patent: 5001280 (1991-03-01), Gubelmann et al.
patent: 5055623 (1991-10-01), Gubelmann et al.
patent: 5077026 (1991-12-01), Nair et al.
patent: 5098687 (1992-03-01), Skeels et al.
patent: 5110995 (1992-05-01), Kharitonov et al.
patent: 5367099 (1994-11-01), Beck et al.
Burch et al., Direct Partial Oxidation Of Benzene To Phenol On Zeolite Catalyst, Applied Catalysis A: General, 86:139-146 (1992).
Burch et al., Investigation Of Zeolite Catalysts For The Direct Partial Oxidation Of Benzene To Phenol, Applied Catalysis A: General, 103:135-162 (1993).
Burch et al., Factors Affecting The Deactivation Of Various Zeolites Used As Catalysts For The Direct Partial Oxidation Of Benzene To Phenol, Applied Catalysis A: General, 106:167-183 (1993).
Iwamoto et al., Catalytic Oxidation By Oxide Radical Ions. 1. One-Step Hydroxylation Of Benzene To Phenol Over Group 5 and 6 Oxides Supported On Silica Gel, Journal Of Physical Chemistry, 87:903-905 (1983).
Kharitonov et al., Ferrisilicate Analogs Of ZSM-5 Zeolite As Catalysts For One-Step Oxidation Of Benzene To Phenol, Applied Catalysis A: General, 98:33-43 (1993).
Ono et al., Functionalization Of Benzene By Its Reaction With Nitrogen Oxides Over Solid-Acid Catalysts, Heterogeneous Catalysis And Fine Chemicals, 75-82 (1988).
Panov et al., The Role of Iron in N.sub.2 O Decomposition on ZSM-5 Zeolite and Reactivity of the Surface Oxygen Formed, Journal of Molecular Catalysis 61:85-97 (1990).
Panov et al., Oxidation Of Benzene To Phenol By Nitrous Oxide Over Fe-ZSM-5 Zeolites, Applied Catalysis A: General, 82:31-36 (1992).
Panov et al., Oxidative Hydroxylation Using Dinitrogen Monoxide: A Possible Route For Organic Synthesis Over Zeolites, Applied Catalysis A: General, 98:1-20 (1993).
Sobolev et al., Catalytic Properties Of ZSM-5 Zeolites in N.sub.2 O Decomposition: The Role Of Iron, Journal Of Catalysis, 139:435-443 (1993).
Sobolev et al., Stoichiometric Reaction Of Benzene With .alpha.-form Of Oxygen On Fe ZSM-5 Zeolites. Mechanism Of Aromatics Hydroxylation By N.sub.2 O, Journal Of Molecular Catalysis, 84:117-124 (1993).
Suzuki et al., Hydroxylation Of Benzene With Dinitrogen Monoxide Over H-ZSM-5 Zeolite, Chemistry Letters--Japan, 953-956 (1988).
Zholobenko, Preparation Of Phenol Over Dehydroxylated HZSM-5 Zeolites, Mendeleev Commun., 28-29 (1993).
Kharitonov Alexander Sergeevich
Panov Gennady Ivanovich
Pirutko Larisa Vladimirovna
Sheveleva Galina Anatolievna
Sobolev Vladimir Ivanovich
Geist Gary
Padmanabhan Sreeni
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