Catalysts for polymerizing propylene in a high temperature solut

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252429B, 526152, 526351, C08F 206, C08F 1006

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active

042974658

ABSTRACT:
This invention relates to improved catalysts for the polymerization of propylene and higher .alpha.-olefin in a high temperature solution process comprising (1) a beta amino carboxylic ester, (2) an aluminum trialkyl and (3) a transition metal halide. More particularly, this invention relates to catalysts for the catalytic high temperature solution polymerization of .alpha.-mono-olefins containing at least 3 carbon atoms to form solid, highly crystalline polymers. More specifically, the catalysts of the present invention produce polypropylene in a high temperature solution process at very high polymer to catalysts yields.

REFERENCES:
patent: 2965627 (1960-12-01), Field et al.
patent: 3219648 (1965-11-01), Hill
patent: 4187196 (1980-02-01), Giannini et al.

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